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ENVIRONMENTAL AND HEALTH ISSUES FOR
Stat-X AEROSOL GENERATORS
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ENVIRONMENTAL ISSUES
There are no environmental issues associated with the use of Stat-X aerosol
generators. Both the Ozone Depletion Potential (ODP) and Global Warming
Potential (GWP) are zero.
TOXICITY AND HEALTH ISSUES
Aerosol generators do not present a health hazard in their benign state - as the constituent chemicals are pressed into a solid form that is extremely stable - even at elevated operating temperatures. There are no environmental or health hazards from the chemical in storage.
Unlike gaseous agents, the aerosol does not decompose in the presence of fire
nor does it extinguish by oxygen deprivation. Stat-X suppresses fire (primarily) by chemical interference with the “Fire Propagation” radicals (OH, H, and O) that are essential elements in the expansion of the fire. Stat-X interacts rapidly with these free radicals within the fire zone – thus interrupting the on-going fire reaction.
The aerosol, itself, consists of solid and gas combustion products. The solid
phase is composed of highly dispersed particles of salts and oxides of alkaline
metals that present insignificant health hazards for humans at normal design
concentrations. The gas phase may contain small amounts of carbon monoxide
CO, carbon dioxide CO2, nitrogen oxides NOX, and ammonia NH3. Production of
these gases is minimal in the case of Stat-X due to its patented construction,
chemical formulation, and its manufacture in the United States using only technical and reagent grade chemicals. In tests conducted by a certified,
accredited testing facility in the United States, Stat-X generators were shown
to produce gas levels several orders of magnitude less than the standard
allowed for automobile airbag systems for passenger vehicles (See Figure 1).
Tests have shown no long-term negative effects from exposure to the aerosol.
While the components of the aerosol are not considered toxic at normal
concentration levels, ingestion of the ultra-fine particulate may cause shortterm
discomfort and unnecessary exposure should be avoided. Studies conducted to date, indicate that any potential toxicological issues with the aerosols in general are related to possible elevated levels of potentially harmful products that may be produced in the gas phase – such as, CO, NOx, etc. - and not due to the influence of the solid particulate.1,2 In the case of Stat-X , in particular, the effect is negligible due to the extremely low level of gas production (See Figure 1).
In tests conducted by VNIIPO (Russian State Fire Protection Institute), the
aerosol was considered to have the same acute toxicity as Halon 13013. The
Toxicology Institute of the Public Health and Medical Department of the Russian Federation and tests conducted by the Institute of Biophysics (Department of Public Health and Medicine Russian Federation), as well as others, have shown that the aerosol does not present a health hazard due to limited accidental exposure at normal design concentrations.
Exposure to the aerosol is generally of less concern than is exposure to the decomposition products of a fire. Accidental exposures under five minutes are normally considered safe. Certain safety restrictions, however, should always be observed. Exposure to the aerosol should be avoided as ingestion of the ultrafine particulate may cause short-term discomfort. The discharge of the aerosol also has a relatively high obscuration factor. As a result, the following system installation requirements must be observed.
SYSTEM INSTALLATION REQUIREMENTS
Stat-X total flood systems shall only be applied in occupied areas in conjunction with a 30 second time delay and system isolate switch to
insure egress of personnel prior to system discharge and manual only
activation whenever personnel may be present in the protected
volume.
1 E.A. Smith, E.C. Kimmel , et al, “Toxological Evaluation of Exposure to Two Formulations of a Pyrotechnically-Generated Aerosol: Range Finding and Multiple Dose”, HOTWC.96
2“Search of Halon Alternatives in Fire Extinguishing” Safety Problems During Emergency Situations, Issue 1-M, 1992, pages 73-79.
3 *Andreev V.A., et al, “Replacement of Halon in Fire Extinguishing Systems”, Proceedings of the Halon Alternatives Technical Working Conference, 1993.
Stat-X Aerosol Physical Properties
Average Values @ 100 gram/m3 Concentration
Gas Products:
(ppm) |
Stat-X
15 minute TWA* |
Automobile-
Airbag Emission
Standard
20 minute
TWA* |
NIOSH
IDLH |
|
| |
|
|
| NOX = NO + NO2 |
2.05 |
60.00 |
120.00 |
|
|
| CO2 |
756.00 |
40,000.00 |
40,000.00 |
|
|
| Solid Particulate: |
|
|
Percent |
|
| |
|
|
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| Other Potassium Compounds |
5.5% |
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| Particle Size Distribution: |
Percent |
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| |
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| Operating and Storage Conditions: |
|
| Humidity |
|
Up to 98% @+35°C |
|
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| Temperature |
|
- 54°C to + 54°C |
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* TWA = Time Weighted Average
Figure 1.0 |